Gas phase acidities of aliphatic carboxylic acids, based on measurements of proton transfer equilibria
نویسندگان
چکیده
منابع مشابه
GAS-PHASE ACIDITY OF SOME CARBOXYLIC ACIDS CALCULATED BY MNDO
Gas-phase acidities of 15 aliphatic carboxylic acids, X CH -,COOH, have been calculated using the MNDO method. Among the substituted groups exist the electron donor alkyl groups and electron acceptor halogens. The average error in acidity is within the experimental uncertainty of the data. Systematic errors have been found for the substituents which form internal hydrogen bondings. A reaso...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1989
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v89-092